Composite manganese oxide percolating networks as a suspension electrode for an asymmetric flow capacitor

Researchers examined the use of a percolating network of metal oxides (MnO2) as the active materials in a suspension electrode as a way to increase the capacitance and energy density of an electrochemical flow capacitor...

Composite manganese oxide percolating networks as a suspension electrode for an asymmetric flow capacitor

Kelsey Bridget Hatzell , Lei Fan , Majid Beidaghi , Muhammad Boota , Ekaterina Pomerantseva , Emin C Kumbur , and Yury Gogotsi

ACS Appl. Mater. Interfaces, Just Accepted Manuscript
DOI: 10.1021/am501650q
Publication Date (Web): April 23, 2014
Copyright © 2014 American Chemical Society

 Abstract

In this study we examine the use of a percolating network of metal oxides (MnO2) as the active materials in a suspension electrode as a way to increase the capacitance and energy density of an electrochemical flow capacitor. Amorphous manganese oxide was synthesized via a low-temperature hydrothermal approach and combined with carbon black to form composite flowable electrodes of different compositions.

All suspension electrodes were tested in static configurations and consisted of an active solid material (MnO2 or Activated Carbon) immersed in aqueous neutral electrolyte (1 M Na2SO4). Increasing concentrations of carbon black led to better rate performance but at the cost of capacitance and viscosity. Furthermore, it was shown that an expanded voltage window of 1.6 V could be achieved when combining a composite MnO2-carbon black (cathode) and an activated carbon suspension (anode) in a charge balanced asymmetric device. The expansion of the voltage window led to a significant increase in the energy density to ~11 Wh kg-1 at a power density of ~50 W kg-1. These values are ~3.5 times and ~2 times better than a symmetric suspension electrode based on activated carbon.

Source: www.pubs.acs.org

 

 

News from MRC.ORG.UA

Researcers from Drexel University have developed a recipe that can turn electrolyte solution into a safeguard against the chemical process that leads to battery-related disasters

Recipe for Safer Batteries — Just Add DiamondsResearchers described a process by which nanodiamonds — tiny diamond particles 10,000 times smaller than the diameter of a hair — curtail the electrochemical deposition, called plating, that can lead to hazardous short-circuiting of lithium ion batteries.

 
Triangle Talks with Yury Gogotsi

alt

Yury Gogotsi is a researcher in the Drexel University Nanomaterials Group. He and his colleagues discovered a series of novel materials known as MXenes. 

 
Yury Gogotsi is the most influential scientist of modern Ukraine

altThe life of Yury Gogotsi is a constant back and forth between the top laboratories in the world, writing articles in the best scientific journals and research materials that can change the world around them. 

 
Professor Yury Gogotsi , Drexel University, USA, received an Honorary Doctorate from Frantsevich Institute for Problems of Materials Science, National Academy of Science of Ukraine, Kiev, Ukraine, June 20, 2017.

Deputy Directors of IPMS NAS professors Dr. Ragulya, Dr. Baglyuk, Mr. Zavorotnyi, Honorary Professor of IPMS NASU Yury Gogotsi,  Scientific Secretary Dr. Kartuzov and Dr. Firstov Professor Yury Gogotsi , Drexel University, USA,  received an Honorary Doctorate from Frantsevich Institute for Problems of Materials Science, National Academy of Science of Ukraine.

 
Professor Yury Gogotsi was speaking about nanotechnology in energy storage at the World Science Festival 2017

Professor Yury Gogotsi at World Science Festival 2017Join world-class nanoscientists and environmental leaders to explore how the capacity to harness molecules and atoms is accelerating spectacular inventions — including light-weight “wonder materials,” vital energy-storage technologies, and new sources of renewable energy — which promise to redefine the very future of energy.

 
MXenes are at the forefront of 2D materials research

alt

Research of 2D MXenes is prominently featured in an article in Chemical & Engineering News - bulletin of the American Chemical Society that goes in hard copy to more than 150,000 subscribers. No doubt, MXenes are at the forefront of 2D materials research.

 
IDEATION Seminars: A New Platform for Innovation Management, Promotion, Licensing, Technology Transfer and Commercialization, June 7 at 14:30, KPI, Kyiv

altSpeakers:  Victor Korsun and Douglas Graham

 
Nano Iguana became a 1st place winner at 2017 MRS Science as Art Competition

Entry Nano Iguana became a 1st place winner at Science as Art Competition 2017: Nano-anatase (TiO2) crystals decorating graphene-like carbon, fabricated by oxidizing 2d Ti3C2 MXene powder, presented by A. J. Drexel Nanotechnology Institute and Department of Materials Science  and Engineering, Drexel University, USAResearch team from Drexel University lead by professor Yury Gogotsi produced an award-wining entry and became the 1st place winner in Science as Art competition at 2017 MRS Spring meeting in Phoenix.

 
1st Africa Energy Materials conference, 28 – 31 March 2017, Pretoria, South Africa

1st Africa Energy Materials conference On the first day of the conference, on March 28, the conference participants had an opportunity to attend a plenary lecture "Two-Dimensional Materials for High Rate and High-energy Density Storage" by invited plenary speaker professor Yury Gogotsi, Distinguished University Professor and Trustee Chair of Materials Science and Engineering at Drexel University, and Director of the A.J. Drexel Nanomaterials Institute 

 
Workshop “Nanomaterials – based innovative engineering solution to ensure sustainable safeguard to indoor air “ NANOGUARD2AR 27-28 February, Lisbon, Portugal

altThe goal of the workshop is to attract the most recognized academic experts in the field of Innovative Nanomaterials for Environmental Application to share their knowledge and expertise on nanomaterials, nanoengineering and green building concepts.

 
MATERIAL WITNESSES — RESEARCHERS AROUND THE WORLD ARE DELVING INTO DREXEL’S 2D MXENE

Researchers from the A.J. Drexel Nanomaterials Institute have been studying MXene for nearly half a decade. (L-R): Olekisy Gogotsi (Director of Materials Research Center, Ukraine), Gabriel Scull, Babak Anasori, Mohamed Alhabeb, Yury Gogotsi.

More than twenty 2D carbides, nitrides and carbonitrides of transition metals (MXenes) have been synthesized and studied, and dozens more predicted to exist. Highly electrically conductive MXenes show promise in electrical energy storage, electromagnetic interference shielding, electrocatalysis, plasmonics and other applications.

 
Prof. Gogotsi has been included in the list of ISI Highly Cited researchers for the 3rd year in the row

altProf. Gogotsi has been named among Highly Cited Researchers 2016, representing worlds most influential scientific minds

 
Appointment ceremony of Honorary professorship for prof. Yury Gogotsi, Jilin University, Changchun, China on October 20, 2016

Honorary professor of Jilin University Yury Gogotsi  and Li Yuanyuan, President of Jilin University, academician of the Chinese Academy of Engineering

The official appointment ceremony of Honorary professorship for Dr. Yury Gogotsi took place in a ceremonial atmosphere at Jilin University, Changchun, Jilin Province, China on October 20, 2016.

 
12th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XII)

12th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XII)12th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XII), is held during 14-19 October, 2016 at Hunan Agriculture University together with Nanjing Tech University, Fudan University and University of Technology, Sydney.

 
Cleaning up electromagnetic pollution by containing the emissions with a thin coating of a nanomaterial called MXene

MXene is a nanomaterial that is both thin and light, but also has the unique ability to block and absorb electromagnetic radiation, which makes it the perfect for use as shielding in electronics devices.

 According to the authors, when electromagnetic waves come in contact with MXene, some are immediately reflected from its surface, while others pass through the surface but they lose energy amidst the material’s atomically thin layers.